Limnic eruption

Imagine a serene lake suddenly boiling over, erupting a silent, invisible cloud of death. This is a limnic eruption — a rare and terrifying natural hazard where vast amounts of dissolved carbon dioxide burst from deep lake waters. It's an event that has claimed thousands of lives, showcasing nature's capacity for silent, sudden devastation, and forcing us to confront the hidden dangers beneath seemingly tranquil surfaces. Limnic eruptions occur when deep, stable lakes become saturated with dissolved gases, often carbon dioxide, under immense pressure. These events are incredibly rare, requiring specific geological and limnological conditions, but when they do occur, they can be devastatingly lethal due to asphyxiation. Scientists have developed innovative degassing methods, essentially creating controlled, miniature eruptions, to prevent future tragedies in these 'exploding lakes'.

Source: Wikipedia

AI Summary

Imagine a serene lake suddenly boiling over, erupting a silent, invisible cloud of death. This is a limnic eruption — a rare and terrifying natural hazard where vast amounts of dissolved carbon dioxide burst from deep lake waters. It's an event that has claimed thousands of lives, showcasing nature's capacity for silent, sudden devastation, and forcing us to confront the hidden dangers beneath seemingly tranquil surfaces.

When Lakes Explode: A Silent Killer

A limnic eruption, sometimes called a 'lake overturn,' is one of nature's most peculiar and deadly phenomena. It's not about fire or brimstone, but an invisible killer: carbon dioxide gas, suddenly bursting forth from the depths of a lake. Imagine the fizz of a soda bottle — but on a scale that can suffocate entire villages.

These rare events were only formally recognized as a distinct hazard after two catastrophic incidents in Cameroon. Scientists realized that while they might be linked to volcanic activity, the danger itself came from the lake's hidden gaseous burden, not directly from magma.

Echoes From the Past

Pinpointing past limnic eruptions is incredibly difficult because their cause — invisible CO2 gas — leaves little direct evidence. However, some historical accounts hint at such events. The Roman historian Plutarch, for instance, described Lake Albano in 406 BC surging inexplicably over its banks, devastating farmland before flowing into the sea. Geologists now suspect volcanic gases trapped deep within the lake were the culprit.

Modern Tragedies in Cameroon

Modern history has unfortunately confirmed these devastating events. The first recorded limnic eruption occurred at Lake Monoun, Cameroon, in 1984. Thirty-seven people lost their lives, suffocated by the sudden release of CO2.

Just two years later, in 1986, a far deadlier eruption struck nearby Lake Nyos. Over 80 million cubic meters of CO2—enough to fill over 30,000 Olympic swimming pools—erupted, creating a dense, suffocating cloud. This silent wave claimed the lives of approximately 1,700 people and 3,000 livestock in a matter of hours, reaching casualties as far as 25 kilometers away.

Ancient Warnings and Future Threats

Even ancient fossil records provide eerie evidence. The Messel Pit in Germany, a UNESCO World Heritage site, contains perfectly preserved fossils from the early Eocene epoch. Among the victims are insects, frogs, birds, and early mammals—all thought to have been asphyxiated by a limnic eruption, frozen in time as they sought breath.

Today, one of the most concerning 'exploding lakes' is Lake Kivu, nestled between the Democratic Republic of the Congo and Rwanda. It's vastly larger than Nyos and Monoun and sits in a highly populated, tectonically active region. Sediment samples from Kivu suggest massive extinction events have occurred roughly every 1,000 years—a chilling reminder of its potential.

What Causes a Lake to Explode?

For a limnic eruption to occur, a lake's deep waters must become nearly saturated with gas, most commonly carbon dioxide. This CO2 can bubble up from volcanic activity beneath the lakebed, or it can be a byproduct of organic material decaying on the bottom.

Think of it like an unopened can of soda. The CO2 is dissolved in the liquid, under pressure. Lakes are similar: the immense pressure at great depths, combined with cooler water temperatures, allows far more CO2 to dissolve than would otherwise be possible. This relationship is described by Henry's Law, which states that the solubility of a gas in a liquid is directly proportional to the partial pressure of that gas above the liquid.

As gas builds up, the water becomes supersaturated—a precarious state. A trigger is then needed to upset this delicate balance. This could be anything from a landslide, an earthquake, or volcanic tremors, to even heavy rain or strong winds that disturb the water layers.

Once triggered, a small pocket of gas-saturated water is lifted to a shallower depth. Here, the pressure is lower, and the CO2 can no longer remain fully dissolved. It 'exsolves' as bubbles, which rapidly expand. The buoyancy of these bubbles further lifts the water, creating a runaway chain reaction that pulls more gas-laden water from below. This process results in a towering fountain of gas and water, discharging the lethal CO2 into the atmosphere and potentially generating a tsunami-like wave.

Why Are They So Rare?

Limnic eruptions are exceptionally rare for several reasons. First, a strong source of CO2 is needed, usually in volcanically active regions. Second, the lake must be meromictic—meaning its water layers don't mix regularly. Most lakes are holomictic, mixing their layers annually and releasing any dissolved gases harmlessly. Only about one in a thousand lakes is meromictic, creating the stable stratification necessary for gas buildup.

Finally, the lake must be sufficiently deep. Greater depth means greater pressure, which in turn allows for a much larger volume of CO2 to dissolve into the water before saturation is reached, setting the stage for a truly catastrophic release.

The Aftermath: A Cloud of Death

Once a limnic eruption occurs, a massive cloud of CO2 forms above the lake. Carbon dioxide is denser than air, so it sinks, clinging to the ground and displacing breathable oxygen. Victims, primarily from asphyxiation, quickly succumb. The CO2 can also make bodily fluids acidic, and in a cruel twist, gasping for air only accelerates the inhalation of the toxic cloud.

At Lake Nyos, the cloud descended into a nearby valley, killing nearly everyone in its path. While initial theories suggested acidic components, later research pointed to extreme oxygen deprivation causing blisters on victims' skin due to pressure ulcers. The force of the eruption itself was also immense, creating a 24-meter-high tsunami that scoured vegetation from the lake's immediate shores.

Preventing Future Disasters: Controlled Degassing

To prevent future tragedies, scientists embarked on an ambitious project: controlled degassing. Led by French scientist Michel Halbwachs, teams began experimenting at Lake Monoun and Lake Nyos in the 1990s, using a network of siphons to safely release the gas.

The process is ingenious: a pipe is lowered vertically into the lake, reaching deep into the gas-saturated water. A small amount of water is initially pumped to the surface to start the flow. Once it reaches the lower pressure near the surface, the dissolved CO2 begins to bubble out. The natural buoyancy of these rising bubbles then creates a powerful, self-sustaining fountain that draws more gas-rich water up the pipe, continuously degassing the lake in a controlled manner.

This 'pump' is essentially a miniature, controlled limnic eruption. However, the deep lake waters are slightly acidic due to the dissolved CO2, which can corrode the pipes and monitoring equipment, requiring ongoing maintenance. There's also a minor concern that the released CO2 could briefly settle on the lake's surface, affecting wildlife, though the controlled nature of the release minimizes this risk.

Success Stories and Ongoing Efforts

In 2001, a single pipe was installed at Lake Nyos, with two more added in 2011 with UN support. Lake Monoun received its first pipe in 2003, and two more in 2006. These pipes are estimated to remove roughly the same amount of gas that naturally enters the lakes, preventing further dangerous buildup. Indeed, an 18-month project effectively degassed Lake Monoun, rendering it safe.

Interestingly, even non-meromictic lakes can show hints of this process. There's evidence that Lake Michigan in the United States spontaneously degasses on a much smaller scale each fall, a gentle reminder of the powerful forces at play beneath the surface.

The Lake Kivu Challenge

Lake Kivu remains the greatest concern. It's not only 1,700 times larger than Lake Nyos but also home to over two million people along its shores. The region's active armed conflicts and limited state capacity further complicate efforts to study and mitigate the risk.

While Lake Kivu hasn't reached saturation yet, its surface temperature is steadily rising, and it lies dangerously close to potential triggers like the active Mount Nyiragongo volcano and a major earthquake zone. If a full limnic eruption were to occur here, the scale of the disaster could be unprecedented, potentially affecting millions.

Degassing Lake Kivu is a monumental task, estimated to cost millions of dollars due to its immense size and gas volume. However, an innovative solution is underway: harnessing the lake's methane. Since 2010, projects have been extracting methane from the lake to generate electricity in Rwanda. This process, known as catalyst scrubbing, also removes some CO2 as a beneficial side effect.

It's a clever dual-purpose initiative: providing much-needed energy while reducing a deadly natural hazard. Yet, it remains uncertain whether enough gas will be removed through these efforts to completely eliminate the risk of a future limnic eruption at Lake Kivu. The silent threat still looms.

Article

Limnic eruption

Lake Nyos, the site of a limnic eruption in 1986

A limnic eruption, also known as a lake overturn, is an extremely rare type of natural hazard in which dissolved carbon dioxide (CO2) suddenly erupts from deep lake waters, forming a gas cloud capable of asphyxiating wildlife, livestock, and humans. Scientists believe earthquakes, volcanic activity, and other explosive events can serve as triggers for limnic eruptions as the rising CO2 ejects water from the lake. Lakes in which such activity occurs are referred to as limnically active lakes or exploding lakes. Some features of limnically active lakes include:

• CO2-saturated incoming water • A cool lake bottom indicating an absence of direct volcanic heat with lake waters • An upper and lower thermal layer with differing CO2 saturations • Proximity to areas with volcanic activity

Investigations of the Lake Monoun and Lake Nyos casualties led scientists to classify limnic eruptions as a distinct type of hazard event, even though they can be indirectly linked to volcanic eruptions.

Historical occurrences

Limnic eruption

Due to the largely invisible nature of the underlying cause (CO2 gas) behind limnic eruptions, it is difficult to determine to what extent, and when, eruptions have occurred in the past. The Roman historian Plutarch reports that in 406 BC, Lake Albano surged over the surrounding hills, despite there being no rain nor tributaries flowing into the lake to account for the rise in water level. The ensuing flood destroyed fields and vineyards before eventually pouring into the sea. This event is thought to have been caused by volcanic gases, trapped in sediment at the bottom of the lake and gradually building up until suddenly releasing, causing the water to overflow.

In recent history, this phenomenon has been observed twice. The first recorded limnic eruption occurred in Cameroon at Lake Monoun in 1984, causing asphyxiation and death of 37 people living nearby. A second, deadlier eruption happened at neighboring Lake Nyos in 1986, releasing over 80 million m3 of CO2, killing around 1,700 people and 3,000 livestock, again by asphyxiation.

A third lake, the much larger Lake Kivu, rests on the border between the Democratic Republic of the Congo and Rwanda, and contains massive amounts of dissolved CO2. Sediment samples taken from the lake showed an event caused living creatures in the lake to go extinct around every 1,000 years, and caused nearby vegetation to be swept back into the lake. Limnic eruptions can be detected and quantified on a CO2 concentration scale by taking air samples of the affected region.

Lake Monoun situated in the West Region of Cameroon

The Messel pit fossil deposits of Messel, Germany, show evidence of a limnic eruption there in the early Eocene. Among the victims are perfectly preserved insects, frogs, turtles, crocodiles, birds, anteaters, insectivores, early primates, and paleotheres.

Causes

Limnic eruption

Diagram describing the occurrence of limnic eruption

For a lake to undergo a limnic eruption, the water must be nearly saturated with gas. CO2 was the primary component in the two observed cases, Lake Nyos and Lake Monoun. In Lake Kivu's case, scientists, including lake physicist Alfred Johny Wüest, were also concerned about the concentrations of methane. CO2 may originate from volcanic gas emitted from under the lake, or from decomposition of organic material.

Before a lake becomes saturated, it behaves like an unopened carbonated soft drink: the CO2 is dissolved in the water. In both lakes and soft drinks, CO2 dissolves much more readily at higher pressure due to Henry's law. When the pressure is released, the CO2 comes out of solution as bubbles of gas, which rise to the surface. CO2 also dissolves more readily in cooler water, so very deep lakes can dissolve very large amounts of CO2 since pressure increases, and temperature decreases, with depth. A small increase in water temperature can lead to the release of a large amount of CO2.

Once a lake is saturated, it is very unstable but a trigger is needed to actually set off an eruption. In the case of the 1986 Lake Nyos eruption, landslides were the suspected triggers, but a volcanic eruption, an earthquake, or even wind and rain storms can be potential triggers. Limnic eruptions can also be caused by gradual gas saturation at specific depths triggering spontaneous gas development. Regardless of cause, the trigger pushes gas-saturated water higher in the lake, where the reduced pressure is insufficient to keep gas in solution. The buoyancy from the resulting bubbles lifts the water even higher, releasing yet more bubbles. This process forms a column of gas, at which point the water at the bottom is pulled up by suction, and it too loses CO2 in a runaway process. This eruption discharges the gas into the air and can displace enough water to form a tsunami.

Limnic eruptions are exceptionally rare for several reasons. First, a CO2 source must exist; regions with volcanic activity are most at risk. Second, the vast majority of lakes are holomictic (their layers mix regularly), preventing a buildup of dissolved gases. Only meromictic lakes are stratified, allowing CO2 to remain dissolved. It is estimated only one meromictic lake exists for every 1,000 holomictic lakes. Finally, a lake must be very deep in order to have sufficiently pressurized water that can dissolve large amounts of CO2.

Consequences

Limnic eruption

Bovine killed by the 1986 limnic eruption at Lake Nyos

Once an eruption occurs, a large CO2 cloud forms above the lake and expands to the surrounding region. Because CO2 is denser than air, it has a tendency to sink to the ground, forcing out breathable air and causing asphyxiation. CO2 can make human bodily fluids highly acidic and potentially cause CO2 poisoning. As victims gasp for air, they actually accelerate asphyxia by inhaling CO2.

At Lake Nyos, the gas cloud descended into a nearby village where it settled, killing nearly everyone; casualties as far as 25 km (16 mi) were reported. A change in skin color on some bodies led scientists to hypothesize the gas cloud may have contained dissolved acid such as hydrogen chloride, though this hypothesis is disputed. Many victims were found with blisters on their skin, thought to have been caused by pressure ulcers, which were likely caused by low blood oxygen levels in those asphyxiated by carbon dioxide. Nearby vegetation was largely unaffected, except any growing immediately adjacent to the lake. There, vegetation was damaged or destroyed by a 24-metre-high (79 ft) tsunami caused by the violent eruption.

Degassing

Limnic eruption

Efforts are underway to develop a solution for removing the gas from these lakes and to prevent a build-up which could lead to another disaster. A team led by French scientist Michel Halbwachs began experimenting at Lake Monoun and Lake Nyos in 1990 using siphons to degas the waters of these lakes in a controlled manner. The team positioned a pipe vertically in the lake with its upper end above the water surface. Water saturated with CO2 enters the bottom of the pipe and rises to the top. The lower pressure at the surface allows the gas to come out of solution. Only a small amount of water must be mechanically pumped initially through the pipe to start the flow. As saturated water rises, the CO2 comes out of solution and forms bubbles. The natural buoyancy of the bubbles draws the water up the pipe at high velocity resulting in a fountain at the surface. The degassifying water acts like a pump, drawing more water into the bottom of the pipe, and creating a self-sustaining flow. This is the same process which leads to a natural eruption, but in this case it is controlled by the size of the pipe.

Each pipe has a limited pumping capacity and several would be required for both Lake Monoun and Lake Nyos to degas a significant fraction of the deep lake water and render the lakes safe. The deep lake waters are slightly acidic due to the dissolved CO2 which causes corrosion to the pipes and electronics, necessitating ongoing maintenance. There is some concern that CO2 from the pipes could settle on the surface of the lake forming a thin layer of unbreathable air and thus potentially causing problems for wildlife.

In January 2001, a single pipe was installed by the French-Cameroonian team on Lake Nyos, and two more pipes were installed in 2011 with funding support from the United Nations Development Programme. A pipe was installed at Lake Monoun in 2003 and two more were added in 2006. These three pipes are thought to be sufficient to prevent an increase in CO2 levels, removing approximately the same amount of gas that naturally enters at the lake bed. In January 2003, an 18-month project was approved to fully degas Lake Monoun, and the lake has since been rendered safe.

There is some evidence that Lake Michigan in the United States spontaneously degasses on a much smaller scale each fall.

Lake Kivu risks

Limnic eruption

Satellite image of Lake Kivu in 2003

Lake Kivu is not only about 1,700 times larger than Lake Nyos, but is also located in a far more densely populated area, with over two million people living along its shores. The part within the Democratic Republic of the Congo is a site of active armed conflict and low state capacity for the DRC government, which impedes both studies and any subsequent mitigating actions. Lake Kivu has not reached a high level of CO2 saturation yet; if the water were to become heavily saturated, a limnic eruption would pose a great risk to human and animal life, potentially killing millions.

Two significant changes in Lake Kivu's physical state have brought attention to a possible limnic eruption: the high rates of methane dissociation and a rising surface temperature. Research investigating historical and present-day temperatures show Lake Kivu's surface temperature is increasing by about 0.12 °C per decade. Lake Kivu is in close proximity to potential triggers: Mount Nyiragongo (an active volcano which erupted in January 2002 and May 2021), an active earthquake zone, and other active volcanoes.

While the lake could be degassed in a manner similar to Lake Monoun and Lake Nyos, due to the size of Lake Kivu and the volume of gas it contains, such an operation would be expensive, running into the millions of dollars. A scheme initiated in 2010 to use methane trapped in the lake as a fuel source to generate electricity in Rwanda has led to a degree of CO2 degassing. During the procedure for extracting the flammable methane gas used to fuel power stations on the shore, some CO2 is removed in a process known as catalyst scrubbing. It is unclear whether enough gas will be removed to eliminate the danger of a limnic eruption at Lake Kivu.